Capital! Old guy playing the field (5)
I believe the answer is:
romeo
'guy playing the field' is the definition.
I can't tell whether this defines the answer.
'capital old' is the wordplay.
'capital' becomes 'rome' (capital of Italy).
'old' becomes 'o' (abbreviation).
'rome'+'o'='ROMEO'
Can you help me to learn more?
(Other definitions for romeo that I've seen before include "Code word for the letter R" , "Tragic Shakespeare hero" , "Juliet's swain" , "24's lover" , "Shakespearean lover" .)