Captivated by captain getting injured (7)
I believe the answer is:
charmed
'captivated' is the definition.
(synonyms)
'captain getting injured' is the wordplay.
'captain getting' becomes 'c' (I am not sure about this - if you are sure you should give a lot more credence to this answer).
'injured' becomes 'harmed' (similar in meaning).
'c'+'harmed'='CHARMED'
'by' acts as a link.
Can you help me to learn more?
(Other definitions for charmed that I've seen before include "Entranced" , "Unusually lucky" , "Enchanted" , "blessed by fortune" .)