Capture talent Raphael possesses (6)
I believe the answer is:
entrap
'capture' is the definition.
(entrapping is a kind of capturing)
'talent raphael possesses' is the wordplay.
'possesses' indicates the answer is hidden within the clue.
'ENTRAP' is hidden within 'talent raphael'.
(Other definitions for entrap that I've seen before include "decoy" , "Parent (anag)" , "Lure into wrongdoing in order to arrest" , "Frame -- stitch up" , "Catch - frame" .)