Captured at work (8)
I believe the answer is:
occupied
This clue is a double definition.
'captured' is the first definition.
(e.g. an occupied country or castle)
'at work' is the second definition.
(thesaurus)
(Other definitions for occupied that I've seen before include "Full; working" , "Busy or inhabited" , "Lived in" , "Inhabited, held" , "In enemy hands" .)