Catch slowcoach heading off (4)
I believe the answer is:
nail
'catch' is the definition.
(nail can mean to catch or arrest)
I can't explain the rest of the clue.
Can you help me to learn more?
(Other definitions for nail that I've seen before include "Collar -- cop" , "Thin pointed fastener" , "Metal spike with head" , "Apprehend" , "Brad or tack" .)