Centrally placed and possibly bent out a little (7)
I believe the answer is:
between
'centrally placed and' is the definition.
I can't judge whether this definition defines the answer.
'possibly bent out a little' is the wordplay.
'possibly' indicates anagramming the letters.
'out' is an insertion indicator.
'a little' becomes 'wee' (I've seen this before).
'bent' anagrammed gives 'betn'.
'betn' placed around 'wee' is 'BETWEEN'.
Can you help me to learn more?
(Other definitions for between that I've seen before include "Don't tell anyone else..." , "In the space separating two objects" , "In the space separating (items)" , "In the intermediate part" , "needle, not the smallest"" .)