Charlie may leave after knocking back drink (6)
I believe the answer is:
cognac
'drink' is the definition.
(Cognac is an example)
I can't explain the rest of the clue.
Can you help me to learn more?
(Other definitions for cognac that I've seen before include "Brandy as for Napoleon (6)." , "Brandy of the French Charente" , "Liquor" , "Good brandy" , "Type of brandy" .)