Chemical element, if contracted, could be not available (6)
I believe the answer is:
sodium
'chemical element' is the definition.
(sodium is a kind of chemical element)
I can't explain the rest of the clue.
Can you help me to learn more?
(Other definitions for sodium that I've seen before include "The Na in NaCl" , "Common salt is ...... chloride" , "Element discovered by Humphry Davy" , "Element in common salt" , "Atomic number 11" .)