Chief English state (5)
I believe the answer is:
maine
'state' is the definition.
(Maine is an example)
'chief english' is the wordplay.
'chief' becomes 'main' (I've seen this before).
'english' becomes 'e' (abbreviation).
'main'+'e'='MAINE'
(Other definitions for maine that I've seen before include "The USA's Pine Tree State" , "N. US Atlantic state" , "New England state" , "North-easterly US state" , "NE US state" .)