Chief in shock when announced (6)
I believe the answer is:
sheikh
'chief' is the definition.
(I've seen this before)
I can't explain the remainder of the clue.
Can you help me to learn more?
(Other definitions for sheikh that I've seen before include "Leader of an Arab tribe, a Muslim chief" , "Arab leader or prince" , "Broadcast upset" , "Head of Arab tribe, village etc" , "Disturbance of the peace; brawl" .)