Chief supporter to the bitter end (6)
I believe the answer is:
master
'chief' is the definition.
(I know that chief can be written as master)
I can't explain the remainder of the clue.
Can you help me to learn more?
(Other definitions for master that I've seen before include "Lord - controller - teacher" , "Main; overcome; original recording" , "An old one is a great European painter" , "with 1a [NEW] Jacky may have in nursery" , "With 1a [OLD], one who painted" .)