Church musician upset his rector (9)
I believe the answer is:
chorister
'church musician' is the definition.
'chorister' can be an answer for 'musician' (chorister is a kind of musician). I am not certain of the 'church' bit.
'upset his rector' is the wordplay.
'upset' indicates anagramming the letters.
'his'+'rector'='hisrector'
'hisrector' with letters rearranged gives 'CHORISTER'.
Can you help me to learn more?
(Other definitions for chorister that I've seen before include "Choir member" , "Boy singer" , "Boy singing" , "Church, cathedral singer" , "Choirboy or girl" .)