Clue that coffee's on (5)
I believe the answer is:
aroma
'clue that coffee's on' is the definition.
(I've seen this in another clue)
This is the entire clue.
(Other definitions for aroma that I've seen before include "Pleasant odour" , "Distinctive odour" , "Subtle quality" , "Savour" , "Scent - smell" .)