Collect a great amount (5)
I believe the answer is:
amass
'collect' is the definition.
('amass' can be a synonym of 'collect')
'a great amount' is the wordplay.
'great amount' becomes 'mass'.
'a'+'mass'='AMASS'
(Other definitions for amass that I've seen before include "Build up" , "Be a compiler" , "Collect, hoard" , "Put together" , "Gather in great quantity" .)