Colour of line round centre of Earth (5)
I believe the answer is:
ochre
'colour' is the definition.
(ochre is a kind of colour)
'line round centre of earth' is the wordplay.
'line' becomes 'och' (I can't explain this - if you can you should give a lot more credence to this answer).
'round' becomes 'orb'.
'centre of' says to take the centre.
'earth' becomes 'E'.
The middle of 'orb' is 'r'.
'och'+'r'+'e'='OCHRE'
'of' is the link.
Can you help me to learn more?
(Other definitions for ochre that I've seen before include "Pigment made from clay and iron oxide" , "What gives a yellow colour" , "Orange-yellow colour" , "natural colouring" , "Yellow-red earthy pigment" .)