Complain when a double rum is spilt (6)
I believe the answer is:
murmur
'complain' is the definition.
(I know that murmur is a more specific form of the action complain)
'a double rum is spilt' is the wordplay.
'a double' becomes 'mur' (I am not sure about this - if you are sure you should believe this answer much more).
'is spilt' indicates an anagram.
'rum' is an anagram of 'mur'.
'mur'+'mur'='MURMUR'
'when' is the link.
Can you help me to learn more?
(Other definitions for murmur that I've seen before include "Soft voices (of discontent)" , "Undertone" , "Quietly spoken utterance; heart defect" , "Low background noise" , "Speak softly or indistinctly" .)