Confiscates one thousand sterling (8)
I believe the answer is:
impounds
'confiscates' is the definition.
('impound' can be a synonym of 'confiscate')
'one thousand sterling' is the wordplay.
'one' becomes 'i' (Roman numeral).
'thousand' becomes 'M' (Roman numeral for a thousand).
'sterling' becomes 'pounds' (I can't justify this - if you can you should give a lot more credence to this answer).
'i'+'m'+'pounds'='IMPOUNDS'
Can you help me to learn more?
(Another definition for impounds that I've seen is " Takes into legal custody, like stray horse".)