Confront new cafe (4)
I believe the answer is:
face
'confront' is the definition.
(synonyms)
'new cafe' is the wordplay.
'new' is an anagram indicator.
'cafe' is an anagram of 'FACE'.
(Other definitions for face that I've seen before include "set of features" , "celebrity" , "well-known person" , "Come up against" , "Countenance, visage" .)