Constable's superior as painter we're told (8)
I believe the answer is:
sergeant
'constable's' is the definition.
(thesaurus)
I don't understand the rest of the clue.
Can you help me to learn more?
(Other definitions for sergeant that I've seen before include "Noncommissioned military officer" , "Military or police officer" , "NCO; Death a fell one, Hamlet" , "Soldier and lover in Hardy novel" , "Estrange from junior army officer" .)