Couples from Paris (5)
I believe the answer is:
pairs
'couples' is the definition.
(I know this)
'from paris' is the wordplay.
'from' is an anagram indicator (from the letters).
'paris' is an anagram of 'PAIRS'.
(Other definitions for pairs that I've seen before include "Duos" , "Couples" , "golfing matches" .)