Courageous rogue has left to overcome resistance (7)
I believe the answer is:
valiant
'courageous' is the definition.
('valiant' can be similar in meaning to 'courageous')
I can't explain the rest of the clue.
Can you help me to learn more?
(Other definitions for valiant that I've seen before include "Doughty" , "Courageous, determined" , "Brave - resolute" , "Brave in battle" , "Heroic" .)