Creature never nonplussed? (5)
I believe the answer is:
adder
'creature' is the definition.
(I have seen 'venomous creature' mean 'adder' so perhaps 'creature' could also mean 'adder')
I can't explain the rest of the clue.
Can you help me to learn more?
(Other definitions for adder that I've seen before include "Reptilian" , "Venemous snake" , "1 of 21 [SNAKES]" , "danger in the countryside" , "Totting snake" .)