Crime of a clergyman who's lost his head? (5)
I believe the answer is:
arson
'crime' is the definition.
(crime of illegally starting a fire)
I cannot understand how the rest of the clue works.
Can you help me to learn more?
(Other definitions for arson that I've seen before include "Pyromaniac crime" , "Sonar (anag.)" , "Act of a pyromaniac" , "Criminal activity" , "Criminal pyromania" .)