Criticise a master's hat! (6)
I believe the answer is:
panama
'hat' is the definition.
(I know that Panama is a type of hat)
'criticise a master's' is the wordplay.
'criticise' becomes 'pan' (informal term meaning to criticise heavily).
'master' becomes 'ma' (Master of Arts).
'pan'+'a'+'ma'='PANAMA'
(Other definitions for panama that I've seen before include "isthmus" , "Wide-brimmed hat" , "Great canal in middle America" , "Great canal connecting Atlantic and Pacific" , "Land - hat - cigar" .)