Cruel ambassador with no diplomatic skills (9)
I believe the answer is:
heartless
'cruel' is the definition.
(similar in meaning)
'ambassador with no diplomatic skills' is the wordplay.
'ambassador' becomes 'he' (His or Her Excellency).
'with no diplomatic skills' becomes 'artless' (I can't explain this - if you can you should give a lot more credence to this answer).
'he'+'artless'='HEARTLESS'
Can you help me to learn more?
(Other definitions for heartless that I've seen before include "Completely lacking in feeling" , "Cruel and unfeeling" , "That's very cruel" , "Without pity or feeling, being defective in cardiac way" , "Lacking pity due to cardiac deficiency" .)