Cunning chief (4)
I believe the answer is:
arch
I believe this is a double definition.
'cunning' is the first definition.
(I've seen this before)
'chief' is the second definition.
('arch' can be a synonym of 'chief')
(Other definitions for arch that I've seen before include "Chief - opening with curved top" , "Mischievous - shrewd" , "Clever" , "in short, is out of date" , "Prefix meaning cheif, perhaps enemy" .)