Dante isn't involved in headcount and that hurts (4)
I believe the answer is:
ouch
'that hurts' is the definition.
I cannot understand how the remainder of the clue works.
Can you help me to learn more?
(Other definitions for ouch that I've seen before include "Exclamation of sudden pain" , "Reaction when pricked" , "Ow!" , "Cry of pain" , "Ruby, perhaps once in it" .)