Dared tangle with a snake! (5)
I believe the answer is:
adder
'a snake' is the definition.
(adder is a kind of snake)
'dared tangle' is the wordplay.
'tangle' indicates an anagram.
'dared' anagrammed gives 'ADDER'.
'with' acts as a link.
(Other definitions for adder that I've seen before include "danger in the countryside" , "Dread (anag)" , "calculator?" , "Snake (like an abacus?)" , "Venomous type" .)