Daring pick (5)
I believe the answer is:
pluck
This clue is a double definition.
'daring' is the first definition.
(thesaurus)
'pick' is the second definition.
('pluck' can be a synonym of 'pick')
(Other definitions for pluck that I've seen before include "Play a guitar - prepare a chicken for the pot" , "Remove feathers" , "Nerve" , "Courage - play a harp" , "Courage - defeather" .)