Daydream about smile in ray of light (8)
I believe the answer is:
moonbeam
'ray of light' is the definition.
(moonbeam is a kind of ray of light)
'daydream about smile' is the wordplay.
'daydream about' becomes 'moon' (synonyms. I am not sure about the 'about' bit.).
'smile' becomes 'beam' (beam can mean to smile).
'moon'+'beam'='MOONBEAM'
'in' acts as a link.
Can you help me to learn more?
(Other definitions for moonbeam that I've seen before include "Night light?" , "Ray, not the brightest" , "Pale ray of light" , "reflective illumination" , "A lunar ray of light" .)