Debut? That’s a shock! (5)
I believe the answer is:
start
I believe this clue is a double definition.
'debut?' is the first definition.
(debut is a kind of start)
'that's a shock' is the second definition.
(to give someone a start is to shock them)
(Other definitions for start that I've seen before include "Initiate" , "Take the first step" , "launch" , "Beginning" , "Opening - jump" .)