Declare to be a sure thing (6)
I believe the answer is:
assert
'declare' is the definition.
(asserting is a kind of declaring)
I cannot understand how the rest of the clue works.
Can you help me to learn more?
(Other definitions for assert that I've seen before include "Insist upon (rights etc)" , "Declare or affirm" , "Stares (anag)" , "Confidently say" , "Aver, declare" .)