Designate superior emirate (5)
I believe the answer is:
dubai
'emirate' is the definition.
(Dubai is an emirate of the UAE)
'designate superior' is the wordplay.
'designate' becomes 'dub' (I've seen this in another clue).
'superior' becomes 'ai' (I can't justify this - if you can you should believe this answer much more).
'dub'+'ai'='DUBAI'
Can you help me to learn more?
(Other definitions for dubai that I've seen before include "Middle Eastern destination" , "capital and port" , "Gulf city/state" , "Gulf emirate and port city" , "Country" .)