Detectives have the ability to alarm (6)
I believe the answer is:
dismay
'alarm' is the definition.
(synonyms)
'detectives have the ability' is the wordplay.
'detectives' becomes 'dis' (Detective Inspectors, DIs).
'have the ability' becomes 'may' (I can't justify this - if you can you should give a lot more credence to this answer).
'dis'+'may'='DISMAY'
'to' is the link.
Can you help me to learn more?
(Other definitions for dismay that I've seen before include "Fill with consternation" , "Disappointment" , "Consternation, trepidation" , "Feeling of surprise and discouragement" , "upset" .)