Devious, just like Serpent, to keep one working away (6)

I believe the answer is:
sneaky
'devious' is the definition.
(I've seen this in another clue)
I don't understand the rest of the clue.
Can you help me to learn more?
(Other definitions for sneaky that I've seen before include "Furtive, lacking candour" , "Being furtive or underhanded" , "Furtive, sly" , "Secretive and sly" , "Sly and devious" .)
