Distant, out-of-the-way (6)
I believe the answer is:
remote
This clue is a double definition.
'distant' is the first definition.
(I know that distant can be written as remote)
'out-of-the-way' is the second definition.
(synonyms)
(Other definitions for remote that I've seen before include "Unlikely" , "Distant, aloof" , "Sort of control" , "Detached" , "in the middle of nowhere" .)