Doctor? Yes and No! Perhaps a pretentious “Medical Officer” (5)
I believe the answer is:
quack
'doctor?' is the definition.
(quack is a kind of doctor)
I don't understand how the remainder of the clue works.
Can you help me to learn more?
(Other definitions for quack that I've seen before include "Bogus doctor" , "Mountebank medic" , "Duck's cry or dud doctor" , "Noise of a duck" , "Pseudo doctor" .)