Does it get your foot accustomed to wearing it? (7)
I believe the answer is:
trainer
'it get your foot accustomed to wearing it?' is the definition.
The definition suggests a singular noun which matches the answer.
I can't explain the rest of the clue.
Can you help me to learn more?
(Other definitions for trainer that I've seen before include "Coach; shoe" , "Footwear singularly" , "The odd thing an athlete may leave behind" , "one that helps runner perform" , "Sports coach" .)