Don't start to accept war-god's challenges. (5)
I believe the answer is:
dares
'challenges' is the definition.
(I know this)
'don't start to accept war-god's' is the wordplay.
'start to' says to take the initial letters.
'accept war' becomes 'a' (I am not sure about this - if you are sure you should give a lot more credence to this answer).
'god's' becomes 'Re's' (Re is an example).
The first letter of 'dont' is 'd'.
'd'+'a'+'res'='DARES'
Can you help me to learn more?
(Other definitions for dares that I've seen before include "Ventures" , "Has the courage to do brave or dangerous thing" , "Challenges to do something dangerous" , "''Who ..., wins'' (SAS motto)" , "Risks" .)