Dour, cold safe (9)
I believe the answer is:
charmless
'dour' is the definition.
'cold safe' is the wordplay.
'cold' becomes 'c' (eg on taps).
'safe' becomes 'harmless' ('harmless' can be similar in meaning to 'safe').
'c'+'harmless'='CHARMLESS'
(Other definitions for charmless that I've seen before include "Unattractive" , "Without attractive features" , "Lacking any appeal" , "not winning" .)