Du Maurier's hat had character! (6)
I believe the answer is:
trilby
'character' is the definition.
Although both the answer and definition are singular nouns, I don't understand how one could define the other.
I don't understand the rest of the clue.
Can you help me to learn more?
(Other definitions for trilby that I've seen before include "The singer under the control of the hypnotist Svengali" , "Soft hat with indented crown" , "Style of hat" , "Hat - George du Maurier heroine" , "kind of headgear" .)