Duck to baste -- around medium (4)
I believe the answer is:
smew
'duck' is the definition.
(smew is a kind of duck)
'baste around medium' is the wordplay.
'around' indicates the central letters.
'medium' becomes 'mew' (I am not sure about this - if you are sure you should give a lot more credence to this answer).
The middle letter of 'baste' is 's'.
's'+'mew'='SMEW'
'to' acts as a link.
Can you help me to learn more?
(Other definitions for smew that I've seen before include "Sea duck" , "Diver" , "Species of merganser" , "Small merganser" , "Bird" .)