Elegant: the antithesis of Country and Western? (6)
I believe the answer is:
urbane
'elegant' is the definition.
(thesaurus)
I cannot understand how the rest of the clue works.
(Other definitions for urbane that I've seen before include "Cultured" , "Refined and civilised" , "Suave and sophisticated" , "Suavely elegant" , "Cosmopolitan" .)