Element in UN put me off (9)
I believe the answer is:
neptunium
'element' is the definition.
(I've seen this before)
'in un put me off' is the wordplay.
'off' indicates an anagram.
'in'+'un'+'put'+'me'='inunputme'
'inunputme' with letters rearranged gives 'NEPTUNIUM'.
(Other definitions for neptunium that I've seen before include "Radioactive metal" , "scarce chemical" , "Element named after planet" .)