Enchantress said to have identity problem (5)
I believe the answer is:
witch
'enchantress' is the definition.
(synonyms)
I cannot understand how the remainder of the clue works.
(Other definitions for witch that I've seen before include "One of a coven" , "One supposed to have magical powers" , "Bad speller!" , "Sorceress" , "Broomstick riderof children's tales" .)