Endlessly grim skies start to look most dangerous (8)
I believe the answer is:
riskiest
'most dangerous' is the definition.
('risky' can be similar in meaning to 'dangerous')
'endlessly grim skies start to' is the wordplay.
'endlessly' indicates the central letters (the ends of the words are removed).
'start' means to remove the last letter (I've seen 'starts' mean this).
The middle letters of 'grim' are 'ri'.
'to' with its last letter taken away is 't'.
'ri'+'skies'+'t'='RISKIEST'
'look' acts as a link.
This may not be right. It may belong to another bit of the clue.
Can you help me to learn more?
(Another definition for riskiest that I've seen is " Most dangerous".)