Excellent soldier leaves coat (3)
I believe the answer is:
mac
'coat' is the definition.
(mac is a kind of coat)
I don't understand the rest of the clue.
(Other definitions for mac that I've seen before include "Waterproof raincoat, in short" , "A rainproof" , "Raincoat (colloq.)" , "Overcoat" , "one used in shower?" .)