Exclude fresh bread (5)
I believe the answer is:
debar
'exclude' is the definition.
(synonyms)
'fresh bread' is the wordplay.
'fresh' is an anagram indicator.
'bread' anagrammed gives 'DEBAR'.
(Other definitions for debar that I've seen before include "Exclude, prohibit" , "Refuse to admit" , "Black" , "Blackball" , "Formally prevent" .)