Extra capital (5)
I believe the answer is:
super
I believe this clue is a double definition.
'extra' is the first definition.
(thesaurus)
'capital' is the second definition.
(thesaurus)
(Other definitions for super that I've seen before include "Prefix meaning terrific or great" , "Prefix meaning above or informally great" , "Great; wonderful" , "Excellent; police officer" , "Outstanding" .)