Extra doctor? That's a relief (5)
I believe the answer is:
locum
This might be a double definition.
'extra doctor?' is the first definition.
'locum' can be an answer for 'doctor?' (I've seen this before). I am unsure of the 'extra' bit.
'relief' is the second definition.
(I know that locum is a type of relief)
'that's a' is the link.
Can you help me to learn more?
(Other definitions for locum that I've seen before include "He fills in" , "Stand-in medic" , "Temporary replacement doctor" , "temporary occupant" , "One stands in" .)